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- Title
Discovery of a Robust and Efficient Homogeneous Silver(I) Catalyst for the Cycloaddition of Azides onto Terminal Alkynes.
- Authors
McNulty, James; Keskar, Kunal
- Abstract
A highly efficient, chemically stable, and well-defined homogeneous silver(I) catalyst is reported for the cycloaddition of azides onto terminal alkynes (Ag-AAC reaction). The Ag-AAC reaction occurs at room temperature or with heating to deliver exclusively the corresponding 1,4-triazole. A pronounced ligand effect was discovered through systematic modification to the ligand structure resulting in the discovery of a chemically stable active catalyst for this reaction.
- Publication
European Journal of Organic Chemistry, 2012, Vol 2012, Issue 28, p5462
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201200930