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- Title
Lanthanide Oxide Clusters: From Tetrahedral [Dy<sub>4</sub>(μ<sub>4</sub>-O)]<sup>10+</sup> to Supertetrahedral [Ln<sub>20</sub>(μ<sub>4</sub>-O)<sub>11</sub>]<sup>38+</sup> (Ln=Tb, Dy, Ho, Er).
- Authors
Lin, Wei‐Quan; Liao, Xiao‐Fen; Jia, Jian‐Hua; Leng, Ji‐Dong; Liu, Jun‐Liang; Guo, Fu‐Sheng; Tong, Ming‐Liang
- Abstract
Supertetrahedral clusters: A family of lanthanide oxide supertetrahedral T3 {Ln20} clusters (Ln=Tb, Dy, Ho, Er; see figure) were obtained from the solvothermal reaction of lanthanide(III) salts with polytriazolate ligands that could be methylated and oxidized in situ.
- Subjects
TETRAHEDRAL molecules; RARE earth metals; MICROCLUSTERS synthesis; X-ray crystallography; X-ray diffraction
- Publication
Chemistry - A European Journal, 2013, Vol 19, Issue 37, p12254
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201301397