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- Title
A Modular Approach to Inorganic Phosphazane Macrocycles.
- Authors
Plajer, Alex J.; García ‐ Rodríguez, Raúl; Benson, Callum G. M.; Matthews, Peter D.; Bond, Andrew D.; Singh, Sanjay; Gade, Lutz H.; Wright, Dominic S.
- Abstract
Inorganic macrocycles, based on non-carbon backbones, present exciting synthetic challenges in the systematic assembly of inorganic molecules, as well as new avenues in host-guest and supramolecular chemistry. Here we demonstrate a new high-yielding modular approach to a broad range of trimeric and hexameric S- and Se-bridged inorganic macrocycles based on cyclophosphazane frameworks, using the building blocks [S=(H)P(μ-NR)]2. The method involves the in situ generation of the key intermediate [E
- Subjects
PHOSPHAZANES; MACROCYCLIC compounds; MOLECULAR self-assembly; SUPRAMOLECULAR chemistry; BLOCKS (Building materials); INTERMEDIATES (Chemistry)
- Publication
Angewandte Chemie, 2017, Vol 129, Issue 31, p9215
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201702558