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- Title
SYNTHESIS OF 3-(3-METHOXY-2-NITRO-3- PHENYLPROPYL)-9H-CARBAZOLE FROM FRIEDEL-CRAFTS REACTION.
- Authors
Clementpia, A. Margaret; Nithya, P.; Sivakumar, M. N.
- Abstract
A new method for the Synthesis of 3-(3-methoxy-2-nitro-3-phenylpropyl)-9H-carbazole viaFriedel-Crafts reaction through nitroolefins derivatives. This the first type Friedel-Crafts reaction of the nitroolefin derived from Bayliss- Hillman mediated by con. H2SO4 thus giving a simple synthesis of substituted olefin derivatives. Although various electron deficient alkenes such as α,β-unsaturated carbonyl compounds, nitriles, sulfones and phosphonates have been employed as substrates in the nitroolefin reaction. This technology also opens new opportunity to make application of compounds.
- Subjects
CARBAZOLE; FRIEDEL-Crafts reaction; NITROALKENES; CHEMICAL derivatives; NITRILES
- Publication
Rasayan Journal of Chemistry, 2018, Vol 11, Issue 1, p321
- ISSN
0974-1496
- Publication type
Article
- DOI
10.7324/RJC.2018.1111759