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- Title
Stacking of Sterically Congested Trifluoromethylated Aromatics in their Crystals – The Role of Weak F···π or F···F Contacts.
- Authors
Yi, Hai; Albrecht, Markus; Pan, Fangfang; Valkonen, Arto; Rissanen, Kari
- Abstract
Five electron‐deficient aromatic compounds bearing 3,5‐bis(trifluoromethyl)benzyl moieties were investigated by X‐ray diffraction. In the crystals, the stacking of π systems between non‐planar electron‐deficient aromatics leads to an assembly with weak F···π and/or F···F interactions as the controlling factor.
- Subjects
CRYSTALS; ELECTRON-deficient compounds; AROMATIC compounds; MOIETIES (Chemistry); X-ray diffraction
- Publication
European Journal of Organic Chemistry, 2020, Vol 2020, Issue 38, p6073
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.202001008