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- Title
Synthesis and Initiation Capabilities of Energetic Diazodinitrophenols.
- Authors
Izsák, Dániel; Klapötke, Thomas M.; Preimesser, Andreas; Stierstorfer, Jörg
- Abstract
The diazophenols 3-amino-6-diazo-2,4-dinitrophenol (4) and 3-chloro-6-diazo-2,5-dinitrophenol (8) were synthesized and comprehensively characterized. The regio-selectivity of nitration reactions with N,N'-(1,4-phenylene)dimethanesulfonamide (1) and N,N'-(1,4-phenylene)diacetamide (6) was investigated in detail. The purity of the products was confirmed via low temperature X-ray diffraction, multinuclear NMR spectroscopy, and elemental analysis. Moreover, the capability of 4 and 8 to initiate RDX (1,3,5-trinitro-1,3,5-triazinane) was tested, together with the two other recently presented diazophenols 4-diazo-2,6-dinitrophenol (iso-DDNP) and 3-hydroxy-DDNP (HODDNP). The tests revealed superior properties of HODDNP compared to DDNP and the other tested diazophenols regarding its ability to initiate RDX.
- Subjects
NITROPHENOLS; NITRO compounds; PHENOLS; LAMPRECID 2770; NITROFEN
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2016, Vol 642, Issue 1, p48
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201500703