We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Plasmonic quantum dots modulated nano-mineral toward photothermal reduction of CO<sub>2</sub> coupled with biomass conversion.
- Authors
Cao, Guangbiao; Xing, Haoran; Gui, Haoguan; Yao, Chao; Chen, Yinjuan; Chen, Yongsheng; Li, Xiazhang
- Abstract
Simultaneous conversion of CO2 and biomass into value-added chemicals through solar-driven catalysis holds tremendous importance for fostering a sustainable circular economy. Herein, plasmonic Bi quantum dots were immobilized on phosphoric acid modified attapulgite (P-ATP) nanorod using an in-situ reduction–deposition method, and were employed for photocatalytic reduction of CO2 coupled with oxidation of biomass-derived benzyl alcohol. Results revealed that Bi atoms successfully integrated into the basal structure of P-ATP, forming chemically coordinated Bi–O–Si bonds that served as efficient transportation channels for electrons. The incorporation of high-density monodispersed Bi quantum dots induced a surface plasmon resonance (SPR) effect, expanding the light absorption range into the near-infrared region. As a consequence, the photo-thermal transformation was significantly accelerated, leading to enhanced reaction kinetics. Notably, 50% Bi/P-ATP nanocomposite exhibited the highest plasmon-mediated photocatalytic CH4 generation (115.7 µmol·g−1·h−1) and CO generation (44.9 µmol·g−1·h−1), along with remarkable benzaldehyde generation rate of 79.5 µmol·g−1·h−1 in the photo-redox coupling system under solar light irradiation. The hydrogen protons released from the oxidation of benzyl alcohol facilitated the incorporation of more hydrogen protons into CO2 to form key CH3O− intermediates. This work demonstrates the synergistic solar-driven valorization of CO2 and biomass using natural mineral based catalyst.
- Subjects
BIOMASS conversion; IRRADIATION; QUANTUM dots; SURFACE plasmon resonance; PLASMONICS; BENZYL alcohol; BIOMASS chemicals; ALCOHOL oxidation
- Publication
Nano Research, 2024, Vol 17, Issue 6, p5061
- ISSN
1998-0124
- Publication type
Article
- DOI
10.1007/s12274-024-6521-9