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- Title
Stereoselective β- C-Glycosylation by a Palladium-Catalyzed Decarboxylative Allylation: Formal Synthesis of Aspergillide A.
- Authors
Zeng, Jing; Ma, Jimei; Xiang, Shaohua; Cai, Shuting; Liu, Xue‐Wei
- Abstract
Mild and sweet: The title reaction proceeds under mild conditions with high regio‐ and diastereoselectivity (see scheme, PG=protecting group, DiPPF=1,1′‐bis(diisopropylphosphino)ferrocene). This reaction is suitable for a wide range of glycal‐derived γ‐ketone esters and affords C‐glycosides with exclusive β‐selectivity. The method was further applied to a concise formal synthesis of aspergillide A.
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 19, p5134
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201210266