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- Title
Palladium-Catalyzed Direct CH Functionalization of Benzoquinone.
- Authors
Walker, Sarah E.; Jordan-Hore, James A.; Johnson, David G.; Macgregor, Stuart A.; Lee, Ai-Lan
- Abstract
A direct Pd-catalyzed CH functionalization of benzoquinone (BQ) can be controlled to give either mono- or disubstituted BQ, including the installation of two different groups in a one-pot procedure. BQ can now be directly functionalized with aryl, heteroaryl, cycloalkyl, and cycloalkene groups and, moreover, the reaction is conducted in environmentally benign water or acetone as solvents.
- Subjects
PALLADIUM; BENZOQUINONES; AROMATIC compounds; CYCLOALKYL group; CYCLOALKENES
- Publication
Angewandte Chemie International Edition, 2014, Vol 53, Issue 50, p13876
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201408054