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- Title
Aromatic Ketones as Mild Presodiating Reagents toward Cathodes for High‐Performance Sodium‐Ion Batteries.
- Authors
Zhang, Shihao; Wang, Jing; Chen, Kean; Pu, Xiangjun; Zhu, Huiying; Zhao, Yanan; Zhao, Along; Chen, Xiaoyang; Fang, Yongjin; Chen, Zhongxue; Cao, Yuliang
- Abstract
Chemical presodiation (CP) is an effective strategy to enhance energy density of sodium ion batteries. However, the sodiation reagents reported so far are basically polycyclic aromatic hydrocarbons (PAHs) wth low reductive potential (~0.1 V vs. Na+/Na), which could easily cause over‐sodiation and structural deterioration of the presodiated cathodes. In this work, Aromatic ketones (AKs) are rationally designed as mild presodiating reagents by introducing a carbonyl group (C=O) into PAHs to balance the conjugated and inductive effect. As the representatives, two compounds 9‐Fluorenoneb (9‐FN) and Benzophenone (BP) manifest favorable equilibrium potential of 1.55 V and 1.07 V (vs. Na+/Na), respectively. Note that 9‐FN demonstrates versatile presodiating capability toward multiple Na uptake hosts (tunneled Na0.44MnO2, layered Na0.67Ni0.33Mn0.67O2, polyanionic Na4Fe2.91(PO4)2P2O7, Na3V2(PO4)3 and Na3V2(PO4)2F3), enabling greatly improved initial charging capacity of the cathode to balance the irrevisible capacity of the anode. Our results indicate that the Aromatic ketones are competitive presodiating cathodic reagents for high‐performance sodium‐ion batteries, and will inspire more studies and application attempts in the future.
- Subjects
SODIUM ions; CATHODES; KETONES; INDUCTIVE effect; POLYCYCLIC aromatic hydrocarbons; HYDROXYBENZOPHENONES; CHEMICAL ionization mass spectrometry; GLOW discharges
- Publication
Angewandte Chemie, 2024, Vol 136, Issue 10, p1
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202317439