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- Title
Selective β-Arylation of Thiophenes with Aryl Iodides Catalyzed by Dinuclear Palladium Carboxylate Complexes.
- Authors
Maki, Yohei; Goto, Takahiro; Tsukada, Naofumi
- Abstract
Novel dinuclear palladium complexes bearing acetoxy ligands were synthesized and characterized by X-ray crystal analysis. The complexes were utilized for the arylation of 2-ethylthiophene with iodobenzene to give ethylphenylthiophenes with high β selectivity. The β-arylation was also applied to a variety of iodoarenes and thiophenes, except those bearing conjugated carbonyl substituents.
- Subjects
THIOPHENES; ARYL iodides; COMPLEX compounds; CHEMICAL reactions; CHEMICAL research
- Publication
ChemCatChem, 2016, Vol 8, Issue 4, p699
- ISSN
1867-3880
- Publication type
Article
- DOI
10.1002/cctc.201501132