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- Title
Rhodium-Catalyzed Sequential Dehydrogenation/Deoxygenation in One-Pot: Efficient Synthesis of Dibenzothiophene Derivatives from Diaryl Sulfoxides.
- Authors
Huang, Qiufeng; Fu, Shurong; Ke, Shaojia; Xiao, Hanbing; Zhang, Xiaofeng; Lin, Shen
- Abstract
A novel strategy for the synthesis of dibenzothiophene derivatives is established through a one-pot intramolecular cross-dehydrogenative-coupling reaction of diaryl sulfoxides followed by deoxygenation with a Rh/Ag catalytic system. The yields obtained were good to excellent (up to 96 %), therefore making the described protocol an attractive option for building dibenzothiophene compounds.
- Subjects
DIBENZOTHIOPHENE; RHODIUM catalysts; DEHYDROGENATION; DEOXYGENATION; DIARYL compounds; SULFOXIDE derivatives
- Publication
European Journal of Organic Chemistry, 2015, Vol 2015, Issue 30, p6602
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201501075