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- Title
Cyclodextrin-Assisted Synthesis of a Metallosupramolecular Terbium(III) Polymer and Its Fluorescence Properties and Chiral Recognition.
- Authors
Yoshihara, Daisuke; Tsuchiya, Youichi; Noguchi, Takao; Yamamoto, Tatsuhiro; Dawn, Arnab; Shinkai, Seiji
- Abstract
Hold and connect! Inclusion of a bridging ligand into cyclodextrin (CD), followed by the addition of TbIII leads to a polyrotaxane‐type metallosupramolecular polymer (see figure, L=4,4′‐biphenyldicarboxylic acid). This polymer can recognize chirality and differentiate enantiomers by fluorescence and circular dichroism spectral changes.
- Subjects
SUPRAMOLECULAR polymers synthesis; CYCLODEXTRINS; CHIRAL recognition; LIGAND exchange reactions; METAL ions; RARE earth metals
- Publication
Chemistry - A European Journal, 2013, Vol 19, Issue 46, p15485
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201302138