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- Title
Crystal Structure of Coordination Polymers Based on A Heterometallic Carboxylate Complex.
- Authors
Sapianik, A. A.; Semenenko, E. E.; Samsonenko, D. G.; Dybtsev, D. N.; Fedin, V. P.
- Abstract
Three new metal-organic frameworks [Zn(Hibdc)2]·DMF (1), (H2NMe2)[Li2Zn3(H2O)(dmf)(Hbtc)3(btc)]·6DMF·H2O (2), and [Li2Zn2(H2O)2(bpp)(bpdc)3]·7DMF (3) are obtained in the interaction of heterometallic carboxylate complex [Li2Zn2(piv)6(py)2] with isophthalic (H2ibdc) and trimesic (H3btc) acids and in the presence of both 4,4′-biphenyldicarboxylic acid (H2bpdc) and 4,4′-bispyridylpropane (bpp). The structure of the obtained compounds is determined by the single crystal X-ray diffraction analysis. In the reactions studied the structure of the initial {Li2Zn2} fragment is not retained. A complicated fragmentation of this four-nuclear block occurs, including the formation of binuclear heterometallic dimers {LiZn}.
- Subjects
CRYSTAL structure; COORDINATION polymers; CARBOXYLATES; METAL-organic frameworks; METAL complexes
- Publication
Journal of Structural Chemistry, 2018, Vol 59, Issue 2, p487
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1134/S0022476618020336