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- Title
Synthesis and crystal structure of 2-(4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropan-2-ol.
- Authors
Li, S.-J.; Shen, D.; Zhang, C.-Z.
- Abstract
The title compound 2-(4-hydroxyphenyl)-1,1,1,3,3,3-hexafluoropropan-2-ol was synthesized by the reaction of phenol with hexafluoroacetone using mesitylene as solvent and. methanesulfonic acid as catalist. The structure is determined by X-ray structure analysis. Two kinds of strong intermolecular hydrogen bonds O( Alk)-H···O( Ar)and O( Ar)-H···O( Alk) are formed in crystal. These hydrogen bonds connect the molecules into two-dimensional layers. Based on theoretical calculations of the electronic structure of the title compound, its application in fluoro-containing materials is predicted. The title compound may be employed to synthesize many organic fluoro-containing polymers, because alcoholic hydroxyl and phenolic hydroxyl are easily deprotonated.
- Subjects
CRYSTAL structure; PROPANE; PHENYL compounds; SOLVENTS; CHEMICAL reactions; HYDROGEN bonding
- Publication
Crystallography Reports, 2015, Vol 60, Issue 6, p874
- ISSN
1063-7745
- Publication type
Article
- DOI
10.1134/S1063774515060176