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- Title
Field-induced orientational switching produces vertically aligned Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXene nanosheets.
- Authors
Lee, Changjae; Park, Soon Mo; Kim, Soobin; Choi, Yun-Seok; Park, Geonhyeong; Kang, Yun Chan; Koo, Chong Min; Kim, Seon Joon; Yoon, Dong Ki
- Abstract
Controlling the orientation of two-dimensional materials is essential to optimize or tune their functional properties. In particular, aligning MXene, a two-dimensional carbide and/or nitride material, has recently received much attention due to its high conductivity and high-density surface functional group properties that can easily vary based on its arranged directions. However, erecting 2D materials vertically can be challenging, given their thinness of few nanometres. Here, vertical alignment of Ti3C2Tx MXene sheets is achieved by applying an in-plane electric field, which is directly observed using polarised optical microscopy and scanning electron microscopy. The electric field-induced vertical alignment parallel to the applied alternating-current field is demonstrated to be reversible in the absence of a field, back to a random orientation distribution. Interdigitated electrodes with uniaxially aligned MXene nanosheets are demonstrated. These can be further modulated to achieve various patterns using diversified electrode substrates. Anisotropic electrical conductivity is also observed in the uniaxially aligned MXene nanosheet film, which is quite different from the randomly oriented ones. The proposed orientation-controlling technique demonstrates potential for many applications including sensors, membranes, polarisers, and general energy applications. In this work, authors demonstrate reversible vertical alignment of Ti3C2Tx MXene sheets induced by an applied in-plane electric field. Further modulation of the field can achieve programmed patterns onto various electrode substrates.
- Subjects
NANOSTRUCTURED materials; SCANNING electron microscopy; SURFACE conductivity; ELECTRIC conductivity; MICROSCOPY
- Publication
Nature Communications, 2022, Vol 13, Issue 1, p1
- ISSN
2041-1723
- Publication type
Article
- DOI
10.1038/s41467-022-33337-2