We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Transition-Metal-Free Transformation of Aryl Bromides into Aromatic Esters and Amides via Aryl Trichloromethyl Ketones.
- Authors
Dohi, Souya; Moriyama, Katsuhiko; Togo, Hideo
- Abstract
A variety of aryl bromides have been treated with Mg and then chloral, followed by tBuOCl and subsequently alcohols or amines to produce the corresponding aromatic esters or amides in good yields via the formation of aryl trichloromethyl ketones as intermediates. These reactions are examples of a transition-metal-free one-pot preparation of aromatic esters and amides from aryl bromides.
- Subjects
ARYL bromides; ESTERS; AMIDES; KETONES; TRICHLOROMETHYL group
- Publication
European Journal of Organic Chemistry, 2013, Vol 2013, Issue 34, p7815
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201301170