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- Title
Synthesis and Properties of two Cu<sup>I</sup> Complexes Involving Tetrathia-fulvalene-Fused Phenanthroline Ligand.
- Authors
Zhi-Gang Niu; Xue-You Wang; Hao-Hua Chen; Xun Wang; Sun Wei; Dong-Min Wu; Guang-Ying Chen; Jie Qin; Gao-Nan Li
- Abstract
Two CuI complexes based on the π-conjugated tetrathiafulvalene-annulated phenanthroline ligands (TTF-Phen, L1 and L2), [CuI(Xantphos)(L1)]BF4 (1, Xantphos = 9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene) and [Cu'(Binap)(L2)]BF4 (2, Binap = 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl), have been synthesized. They have been fully characterized, and their photophysical and electrochemical properties are reported together with those of L1 and L2 for comparison. Both CuI complexes show metal-to-ligand charge transfer (MLCT) absorption bands, whereas the ³MLCT luminescence is strongly quenched.
- Subjects
COPPER compounds synthesis; TETRATHIAFULVALENE; PHENANTHROLINE; LIGANDS (Chemistry); LUMINESCENCE
- Publication
Acta Chimica Slovenica, 2017, Vol 64, Issue 3, p633
- ISSN
1318-0207
- Publication type
Article
- DOI
10.17344/acsi.2017.3423