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- Title
Identification of Gas-phase Pyrolysis Products in a Prescribed Fire: Seminal Detections Using Infrared Spectroscopy for Naphthalene, Methyl Nitrite, Allene, Acrolein and Acetaldehyde.
- Authors
Scharko, Nicole K.; Oeck, Ashley M.; Tonkyn, Russell G.; Myers, Tanya L.; Banach, Catherine A.; Johnson, Timothy J.; Baker, Stephen P.; Lincoln, Emily N.; Chong, Joey; Corcoran, Bonni M.; Burke, Gloria M.; Weise, David R.
- Abstract
Volatile organic compounds (VOCs) are emitted from many sources, including wildland fire; VOCs have received heightened emphasis due to such gases' influential role in the atmosphere, as well as possible health effects. We have used extractive infrared (IR) spectroscopy on recent prescribed burns in longleaf pine stands and herein report seminal detection of five compounds using this technique. The newly reported IR detections include naphthalene, methyl nitrite, allene, acrolein and acetaldehyde. We discuss the approaches used for detection, particularly the software methods needed to fit the analyte and multiple (interfering) spectral components within the selected spectral micro-window(s). We also discuss the method's detection limits and individual species' context in terms of atmospheric chemistry.
- Subjects
PYROLYSIS; INFRARED spectroscopy; METHYL nitrate
- Publication
Atmospheric Measurement Techniques Discussions, 2018, p1
- ISSN
1867-8610
- Publication type
Article
- DOI
10.5194/amt-2018-346