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- Title
An eco-friendly Co(OAc)-catalyzed aerobic oxidation of 4-benzylphenols into 4-hydroxybenzophenones.
- Authors
Huang, Jian-Gang; Guo, Ying; Jiang, Jian-An; Liu, Hong-Wei; Ji, Ya-Fei
- Abstract
An undecorated Co(OAc)-catalyzed aerobic oxidation system has been reported that enables direct transformation of 4-benzylphenols into the corresponding 4-hydroxybenzophenones. The procedure is especially suitable for electron-withdrawing group-containing substrates, which are commonly inefficient to conduct this category of oxidation. Based on well-defined p-benzoquinone methides and the confirmed ethereal intermediate, a plausible mechanism was depicted.
- Subjects
HYDROXYBENZOPHENONES; KETONES; CHEMICAL reactions; ORGANIC compounds; OXO compounds
- Publication
Research on Chemical Intermediates, 2015, Vol 41, Issue 10, p7115
- ISSN
0922-6168
- Publication type
Article
- DOI
10.1007/s11164-014-1801-8