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- Title
Ruthenium‐Catalysed Asymmetric Intramolecular Isomerization/Esterification Reaction: Direct Synthesis of Chiral Dihydrocoumarins.
- Authors
Zhao, Lingzi; Wang, Xuchao; Qiang, Qing; Zhao, Xingwei; Liu, Feipeng; Lu, Shenci; Rong, Zi‐Qiang
- Abstract
Comprehensive Summary: An asymmetric isomerization/intramolecular coupling reaction of allylic alcohols to synthesize chiral dihydrocoumarins was successfully accomplished through ruthenium catalysis. This method demonstrates a wide substrate applicability, excellent tolerance for various functional groups, and good enantioselectivities (up to 90% ee). It provides a convenient pathway to produce a diverse range of structurally distinct chiral dihydrocoumarins in good efficiency.
- Subjects
ISOMERIZATION; COUPLING reactions (Chemistry); ESTERIFICATION; ALLYL alcohol; FUNCTIONAL groups; ASYMMETRIC synthesis
- Publication
Chinese Journal of Chemistry, 2024, Vol 42, Issue 16, p1828
- ISSN
1001-604X
- Publication type
Article
- DOI
10.1002/cjoc.202400084