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- Title
BIS(N,N'-BIS(2-HYDROXYETHYL)ETHYLENEDIAMINE)NICKEL(II) SACCHARINATE: SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURE.
- Authors
Karadogan, Alparslan; Karadag, Ahmet; Yilmaz, Veysel T.
- Abstract
A new nickel(II) saccharinate (sac) complex containing N,N'-bis(2-hydroxyethyl)ethylenediamine (bishydeten), [Ni(bishydeten)2](sac)2, has been synthesized and characterized by elemental analysis, FTIR and single crystal X-ray diffraction. The title complex consists of a [Ni(bishydeten)2]2+ cation and two sac anions. In the complex cation, the nickel(II) ion is coordinated by two neutral bishydeten ligands, leading to a distorted octahedral NiN4O2 coordination, while both sac anions remain outside the coordination sphere. In the crystal, the complex cations and sac anions are connected by an extensive network of N-H⋯N, N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds into a three-dimensional supramolecular lattice.
- Subjects
ETHYLENEDIAMINE; NICKEL compounds; CRYSTAL structure; METAL complexes; COMPLEX compounds synthesis; X-ray diffraction
- Publication
Macedonian Journal of Chemistry & Chemical Engineering, 2015, Vol 34, Issue 1, p1
- ISSN
1857-5552
- Publication type
Article
- DOI
10.20450/mjcce.2015.651