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- Title
Gold(I)-Catalyzed Reaction of Ferrocene and Propargylic Esters: Synthesis of Functionalized Ferrocene Derivatives.
- Authors
López, Enol; Suárez, Tatiana; Ballesteros, Alfredo; López, Luis A.
- Abstract
The reaction of propargylic esters with ferrocene in the presence of gold catalysts provided ferrocene derivatives containing a functionalized vinyl moiety. This ferrocene C-H bond functionalization proceeded with complete regio- and stereoselectivity. The reaction was proposed to proceed through electrophilic substitution, in which a vinylgold carbene intermediate arising from 1,2-rearrangement of the starting propargylic ester would behave as the electrophilic counterpart.
- Subjects
FERROCENE derivatives; GOLD catalysts; ESTER derivatives; STEREOSELECTIVE reactions; ELECTROPHILIC substitution reactions; CARBENE derivatives; CARBON-hydrogen bonds
- Publication
European Journal of Inorganic Chemistry, 2017, Vol 2017, Issue 2, p225
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201600836