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- Title
The Suzuki–Miyaura reaction of BPin-substituted F-BODIPYs with aryl halides.
- Authors
Smith, Craig D.; Thompson, Alison
- Abstract
F-BODIPYs substituted with BPin functionality have been coupled to aryl halides using a mild and efficient catalyst system involving Pd2(dba)3 and XPhos. The methodology enables the Suzuki–Miyaura cross-coupling of electron-rich, electron-poor, and sterically encumbered BPin-substituted F-BODIPYs to aryl halides bearing various functional groups, thus presenting an opportunity for the preparation of highly functionalised F-BODIPYs without need for the corresponding aryl moiety to be available in borylated form.
- Subjects
SUZUKI reaction; ARYL halides; ARYL chlorides; FUNCTIONAL groups; MOIETIES (Chemistry)
- Publication
Canadian Journal of Chemistry, 2021, Vol 99, Issue 3, p287
- ISSN
0008-4042
- Publication type
Article
- DOI
10.1139/cjc-2020-0300