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- Title
Synthesis of Deprenyl-like nitroxide free radicals and their diamagnetic derivatives.
- Authors
Sár, Cecília P.; Kálai, Tamás; Jekő, József; Hideg, Kálmán
- Abstract
Synthesis of paramagnetically modified deprenyl and oxotremorine is reported. Starting from 5- and 6-membered 2,5-disubstituted nitrones 1, 6 or 4-phenyl-2,5,5-trimethyl-1H-pyrroline 1-oxide 11 deprenyl or oxotremorine like nitroxides were synthesized via Grignard reactions. The corresponding pre-nitroxides with propargylamine structure were achieved by reduction of nitroxides followed by methylation.
- Subjects
SELEGILINE; NITROXIDES; FREE radicals; DIAMAGNETISM; NITROXIDE derivatives; OXOTREMORINE; GRIGNARD reagents; CHEMICAL synthesis
- Publication
ARKIVOC: Online Journal of Organic Chemistry, 2012, p47
- ISSN
1551-7004
- Publication type
Article