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- Title
Chiral sulfur-containing structures: Selected synthetic and structural aspects.
- Authors
Drabowicz, Józef; Zając, Adrian; Krasowska, Dorota; Bujnicki, Bogdan; Dudziński, Bogdan; Janicka, Magdalena; Mikołajczyk, Marian; Chmielewski, Marek; Czarnocki, Zbigniew; Gawroński, Jacek; Polavarapu, Prasad L.; Wieczorek, Michał W; Marciniak, Bernard; Sokołowska-Różycka, Ewa
- Abstract
Synthetic procedures applied for the preparation of a new diastereomerically pure sulfinate and amidosulfite and a few enantiomerically pure sulfinyl derivatives, including sulfoxides functionalized with a perfluorocumyl substituent, are presented. Attempts to polymerize optically active 2-(3-thienyl)ethyl p-tolyl sulfoxide are also mentioned. Mechanistic and stereochemical aspects of the presented protocols are discussed. Structural studies, which include the X-ray, circular dichroism, and vibrational circular dichroism--based determinations of the absolute configurations at the stereogenic sulfur atoms and calculations of conformational equilibria for a few model sulfur-containing compounds are also described. The use of optically active t-butylphenylthiophosphinic acid as a chiral solvating agent is illustrated. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:527-536, 2007; Published online in Wiley InterScience (). DOI 10.1002/hc.20335
- Publication
Heteroatom Chemistry, 2007, Vol 18, Issue 5, p527
- ISSN
1042-7163
- Publication type
Other
- DOI
10.1002/hc.20335