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- Title
Selective synthesis of isomeric dithioglycerols.
- Authors
Levanova, E. P.; Grabel'nykh, V. A.; Sukhomazova, E. N.; Zemirova, I. A.; Russavskaya, N. V.; Albanov, A. I.; Klyba, L. V.; Zhanchipova, E. R.; Korchevin, N. A.
- Abstract
Reactions of 2,3-dibromopropan-1-ol and 1,3-dichloropropan-2-ol with elemental sulfur activated in the system hydrazine hydrate-2-aminoethanol at 30–35°C gave oligomeric polysulfides which were subjected to reductive cleavage with formation of individual dithioglycerol isomers. Activation of sulfur with the use of alkali gives rise to mixtures of isomeric products.
- Subjects
DIBROMOPROPANOL phosphate; DICHLOROPROPANE; SULFUR; ETHANOLAMINES; ISOMERASES; ALKALI metals; GLYCERIN
- Publication
Russian Journal of Organic Chemistry, 2008, Vol 44, Issue 10, p1428
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428008100059