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- Title
Rhodium-Catalyzed Borylation/Protonation Tandem Reaction of Hydroxylated Diarylethynes.
- Authors
Yang, Liting; Ma, Jinjin; PENg, Xiaomin; Wang, Danyang; Guo, Tao; Yuan, Bingxin; Li, HENg; Zhang, Panke; Yang, Guanyu
- Abstract
The catalytic synthesis of trans-hydroxystilbenes has a great significance and value in synthetic chemistry and bioscience. To establish a versatile and efficient technology for such reactions, we successfully developed a novel and straightforward way for the construction of E-stilbene derivatives by a rhodium-catalyzed borylation/protonation tandem reaction using H2O as the green hydrogen source. Various E-stilbene derivatives were synthesized with up to 85 % yield.
- Subjects
RHODIUM catalysts; BORYLATION; PROTON transfer reactions
- Publication
Asian Journal of Organic Chemistry, 2017, Vol 6, Issue 6, p698
- ISSN
2193-5807
- Publication type
Article
- DOI
10.1002/ajoc.201700176