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- Title
Synthesis of Spiro[4.5]ecanes by Au(I)‐Catalyzed Vinylogous Conia Ene Reaction.
- Authors
Liu, Fuhai; Ruan, Zhongting; Duan, Xiaoguang; Ma, Ruize; Su, Xujuan; Liang, Ning; Xie, Xingang; She, Xuegong
- Abstract
Au(I) catalysed vinylogous Conia ene reaction was developed to construct the densely functionalized spiro[4.5]‐deca‐1,6‐diene‐8‐ones from easily available 4‐alkyne tethered cyclohex‐2‐enones. 17 substrates with multiple substitutes on the cyclohex‐2‐enone ring were explored to afford the corresponding spiro[4.5]in 52–81 % yields. This reaction features mild conditions, wide substrate scope and atom economic characters.
- Subjects
KONYA (Turkey); ENE reactions; RING formation (Chemistry)
- Publication
European Journal of Organic Chemistry, 2024, Vol 27, Issue 4, p1
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.202301202