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- Title
Vibrational and Electronic Circular Dichroism Study of Chiral Seleno Compounds Prepared from a Naphthol Based Diselenide.
- Authors
Mangiavacchi, Francesca; Mazzeo, Giuseppe; Graziani, Maria Chiara; Marini, Francesca; Drabowicz, Józef; Wielgus, Ewelina; Sancineto, Luca; Longhi, Giovanna; Vivani, Riccardo; Abbate, Sergio; Santi, Claudio
- Abstract
Base induced activation of β‐naphthol toward the electrophilic aromatic substitution has been used for the synthesis of the unprecedented 1,1'‐diselanediylbis(naphthalen‐2‐ol) fully characterized by means of NMR and X‐Ray analysis. Its reactivity was studied and the synthesis of novel chiral selenium containing heterocycles was discovered. Chiroptical methods (VCD and ECD) were successfully used to define their absolute configuration and these results represent the first example reported for organoselenium derivatives.
- Subjects
VIBRATIONAL circular dichroism; NAPHTHOL; ELECTROPHILIC substitution reactions; CIRCULAR dichroism
- Publication
European Journal of Organic Chemistry, 2022, Vol 2022, Issue 23, p1
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.202200282