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- Title
Gold‐Catalyzed Transformation of Ynamides.
- Authors
Shandilya, Shashank; Protim Gogoi, Manash; Dutta, Shubham; Sahoo, Akhila K.
- Abstract
Ynamide, a unique species with inherited polarization of nitrogen lone pair electron to triple bond, has been largely used for the developement of novel synthetic methods and the construction of unusual N‐bearing heterocycles. The reaction versatility of ynamide on umpolung reactivity, radical reactions and asymmetric synthesis have been recently reviewed. This review provides an overall scenic view into the gold catalyzed transformation of ynamides. The ynamides reactivity towards nitrogen‐transfer reagents, such as azides, nitrogen ylides, isoxazoles, and anthranils; oxygen atom‐transfer reagents, like nitrones, sulfoxides, and pyridine N‐oxides; and carbon nucleophiles under gold catalysis are herein uncovered. The scope as well the mechanistic insights of each reaction is also briefed.
- Subjects
YNAMIDES; ASYMMETRIC synthesis; YLIDES; ELECTRON pairs; UMPOLUNG; NITRONES
- Publication
Chemical Record, 2021, Vol 21, Issue 12, p4123
- ISSN
1527-8999
- Publication type
Article
- DOI
10.1002/tcr.202100159