We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Dehydrogenative Silylation of Alkenes for the Synthesis of Substituted Allylsilanes by Photoredox, Hydrogen‐Atom Transfer, and Cobalt Catalysis.
- Authors
Yu, Wan‐Lei; Luo, Yong‐Chun; Yan, Lei; Liu, Dan; Wang, Zhu‐Yin; Xu, Peng‐Fei
- Abstract
A synergistic catalytic method combining photoredox catalysis, hydrogen‐atom transfer, and proton‐reduction catalysis for the dehydrogenative silylation of alkenes was developed. With this approach, a highly concise route to substituted allylsilanes has been achieved under very mild reaction conditions without using oxidants. This transformation features good to excellent yields, operational simplicity, and high atom economy. Based on control experiments, a possible reaction mechanism is proposed.
- Subjects
ALKENE synthesis; ALLYLSILANES; CATALYSIS; SILYLATION; COBALT
- Publication
Angewandte Chemie, 2019, Vol 131, Issue 32, p11057
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201904707