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- Title
Catalytic Direct‐Type Addition Reactions of Alkylarenes with Imines and Alkenes.
- Authors
Yamashita, Yasuhiro; Suzuki, Hirotsugu; Sato, Io; Hirata, Tsubasa; Kobayashi, Shū
- Abstract
Abstract: Catalytic addition reactions of very weakly acidic nonactivated alkylarenes such as toluene and its derivatives were developed by using a strongly basic mixed catalyst system under mild reaction conditions. The addition reactions with imines and alkenes proceeded smoothly under proton‐transfer conditions to afford the desired products in good to high yields, and high levels of regio‐ and stereoselectivity were achieved. It was also revealed that the asymmetric addition reaction of an alkylarene was possible.
- Subjects
ALKYLBENZENES; ADDITION reactions; CATALYTIC activity; IMINES; ALKENES
- Publication
Angewandte Chemie, 2018, Vol 130, Issue 23, p7012
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201711291