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- Title
Ultrafine Metal-Organic Right Square Prism Shaped Nanowires.
- Authors
Otake, Ken‐ichi; Otsubo, Kazuya; Sugimoto, Kunihisa; Fujiwara, Akihiko; Kitagawa, Hiroshi
- Abstract
We report the structural design and control of electronic states of a new series of ultrafine metal-organic right square prism-shaped nanowires. These nanowires have a very small inner diameter of about 2.0 Å, which is larger than hydrogen and similar to xenon atomic diameters. The electronic states of nanowires can be widely controlled by substitution of structural components. Moreover, the platinum homometallic nanowire shows a 100 times higher proton conductivity than a palladium/platinum heterometallic one depending on the electronic states.
- Subjects
ORGANOMETALLIC compounds research; NANOWIRES; HYDROGEN; XENON; PROTON conductivity
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 22, p6558
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201601678