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- Title
Methyl nitroacetate and 3-nitropropionate in the synthesis of hexahydropyrimidines and piperidines.
- Authors
Shakirov, R. R.; Dokichev, T. V.; Biglova, R. Z.; Vlasova, N. M.; Baibulatova, N. Z.; Talipov, R. F.
- Abstract
Treatment of methyl nitroacetate and 3-nitropropionate with formaldehyde and primary amines under Mannich reaction conditions gives 5-nitrohexahydropyrimidines. In the case of methyl nitroacetate both the 5-nitrohexahydropyrimidine and isomeric 3,5-di(methoxycarbonyl)-1-methyl-3,5-dinitropiperidines are formed.
- Subjects
HETEROCYCLIC compounds; FORMALDEHYDE; PYRIMIDINES; MANNICH reaction; CHEMICAL reactions
- Publication
Chemistry of Heterocyclic Compounds, 2008, Vol 44, Issue 1, p43
- ISSN
0009-3122
- Publication type
Article
- DOI
10.1007/s10593-008-0011-y