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- Title
Carbonyliron Complexes of Allenic Acids, Esters, Amides, and Imides.
- Authors
Trifonov, Latchezar S.; Orahovats, Alexander S.; Heimgartner, Heinz
- Abstract
On irradiation in the presence of Fe(CO)5, the allenic amides and imides showed a similar course of complexation to that of esters and lactones, respectively, e.g. the amides of type 10 led to diiron complexes of type 11 ( Scheme 3), whereas the imide 12 yielded a mixture of a dinuclear and two mononuclear complexes ( 13-15, Scheme 4). The racemic ester 6 also gave mononuclear ( 7a, 7b, and 9) and dinuclear complexes (8 a and 8b; Scheme 2). In case of the allenic acid 4, only complexation of type 5 was observed ( Scheme 1).
- Publication
Helvetica Chimica Acta, 1990, Vol 73, Issue 6, p1734
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19900730619