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- Title
Basische Metalle. II. Protonierungs- und Alkylierungsreaktionen von π-Cyclopentadienyl-metall-bis(tert.-phosphit)-Komplexen.
- Authors
Werner, Helmut; Neukomm, Heinrich; Kläui, Wolfgang
- Abstract
Basic Metals. II. Protonation and Alkylation Reactions of π-Cyclopentadienyl-metal-bis(tert.-phosphite) Complexes The complexes C5H5Co[P(OR)3]2 (R = CH3, C2H5) and C5H5Rh[P(OR)3]2 (R = CH3, C2H5, C6H5, C6H4- o-CH3) react with electrophilic agents E+, e.g. H+ and CH3+, to give [C5H5ME(P(OR)3)2]+. Salts of these cation have been isolated with BF4− and PF6− as the anions. The formation of compounds with direct M-H and M-CH3 bonds points to the pronounced Lewis-base properties of the metal atom in the starting complexes. The NMR. data of the cations [C5H5MH(P(OR)3)2]+ and [C5H5MCH3(P(OR)3)2]+ will be discussed.
- Publication
Helvetica Chimica Acta, 1977, Vol 60, Issue 2, p326
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19770600203