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- Title
Ostwald Ripening of Ag<sub>2</sub>Te Precipitates in Thermoelectric PbTe: Effects of Crystallography, Dislocations, and Interatomic Bonding.
- Authors
Yu, Yuan; Sheskin, Ariel; Wang, Zhenyu; Uzhansky, Aleksandra; Natanzon, Yuriy; Dawod, Muhamed; Abdellaoui, Lamya; Schwarz, Torsten; Scheu, Christina; Wuttig, Matthias; Cojocaru‐Mirédin, Oana; Amouyal, Yaron; Zhang, Siyuan
- Abstract
Nanostructuring is important for designing thermoelectrics. Yet, nanoprecipitates are thermodynamically unstable and coarsen through Ostwald ripening. Here, the Ostwald ripening of Ag2Te in PbTe and its resulting impact on thermoelectric performance is investigated. Numerous Guinier‐Preston zones and platelet Ag2Te precipitates in the sample quenched from a single‐phase region is observed. Upon annealing, these platelet precipitates grow into big lath‐shaped second phases by consuming small Ag‐rich clusters. The crystallographic orientation relationships between Ag2Te and PbTe are unraveled by scanning transmission electron microscopy and modeled by first‐principles calculations. The interfaces with low lattice mismatch determine the morphology of Ag2Te in PbTe. Atom probe tomography reveals different chemical bonding mechanisms for PbTe and Ag2Te, which are metavalent and iono‐covalent, respectively. This leads to an acoustic phonon mismatch at the precipitate‐matrix interface. Yet, the electrons are also scattered by these interfaces, resulting in poor electrical properties in the as‐quenched sample. In contrast, the annealed sample contains abundant Ag‐decorated dislocations by activating the Bardeen‐Herring source. These dislocations strongly scatter phonons while maintaining a good electron transmission, contributing to a higher thermoelectric performance. This work demonstrates the complex role of microstructure morphologies, compositions, and bonding mechanisms in thermoelectric response, providing insights into structural design for thermoelectrics.
- Subjects
OSTWALD ripening; THERMOELECTRIC effects; ATOM-probe tomography; SCANNING transmission electron microscopy; CRYSTALLOGRAPHY; ACOUSTIC phonons
- Publication
Advanced Energy Materials, 2024, Vol 14, Issue 19, p1
- ISSN
1614-6832
- Publication type
Article
- DOI
10.1002/aenm.202304442