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- Title
Effect of functionalized graphene on mechanical properties and dielectric constant of bismaleimide composites.
- Authors
Chen, Yufei; Wu, Yunzhong; Dai, Guoqing; Ma, Yingyi
- Abstract
Graphene oxide was obtained by improved Hummers method. Hydrated hydrazine, chitosan or potassium hydroxide was used to prepare different reduced graphene oxide (rGO) in order to choose the best reductant, respectively. The rGO was restored and modified by ionic liquid (NH2IL) to obtain functionalized graphene (NH2IL-rGO), the matrix (MBAE) was synthesized from 4,4′-diamino diphenyl methane bismaleimide modified by diallyl bisphenol A and Bisphenol A bisallyl ether. NH2IL-rGO/MBAE composites were prepared from NH2IL-rGO and MBAE via in situ polymerization, and also studied the effect of NH2IL-rGO on the properties of composites. The results showed that the micro-morphology of composite existed two-phase structure between the matrix and NH2IL-rGO, which gave the material excellent properties. The impact strength and bending strength of the composite reached the maximum and were 15.33 kJ/m2 and 142 MPa, respectively, when the content of NH2IL-rGO was 2 wt%. The thermal decomposition temperature of the composite was 435 °C, the dielectric constant of the composite abruptly reached 84 in the frequency range 102 ~ 105 Hz.
- Subjects
GRAPHENE oxide; PERMITTIVITY; COMPOSITE materials; HYDRAZINE; BISPHENOL A
- Publication
Journal of Materials Science: Materials in Electronics, 2019, Vol 30, Issue 6, p6234
- ISSN
0957-4522
- Publication type
Article
- DOI
10.1007/s10854-019-00926-9