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- Title
Nickel/α‐diimine catalysts in C (sp<sup>2</sup>)–C (sp<sup>2</sup>) homocoupling: An underestimated and versatile ligand family.
- Authors
Kudakina, Vera A.; Asachenko, Andrey F.; Valaeva, Valentina N.; Lebedev, Artyom Y.; Razavi, Abbaz; Mladentsev, Dmitry Y.; Uborsky, Dmitry V.; Voskoboynikov, Alexander Z.
- Abstract
Application of α‐diimine ligands in Ni‐catalyzed reductive homocoupling of haloarenes is reported. The Ni/α‐diimine catalysts are shown to be highly active and allow for preparation of a broad scope of biaryls, including practically important cyclization and polycondensation products. The synthetic availability and versatility of α‐diimines allows for easy tuning of their structure aimed at achieving higher yields of each specific homocoupling product.
- Subjects
CATALYSTS; NICKEL catalysts; ARYL halides; LIGANDS (Chemistry); FAMILIES
- Publication
Applied Organometallic Chemistry, 2024, Vol 38, Issue 4, p1
- ISSN
0268-2605
- Publication type
Article
- DOI
10.1002/aoc.7391