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- Title
A Next‐Generation Air‐Stable Palladium(I) Dimer Enables Olefin Migration and Selective C−C Coupling in Air.
- Authors
Kundu, Gourab; Sperger, Theresa; Rissanen, Kari; Schoenebeck, Franziska
- Abstract
We report a new air‐stable PdI dimer, [Pd(μ‐I)(PCy2tBu)]2, which triggers E‐selective olefin migration to enamides and styrene derivatives in the presence of multiple functional groups and with complete tolerance of air. The same dimer also triggers extremely rapid C−C coupling (alkylation and arylation) at room temperature in a modular and triply selective fashion of aromatic C−Br, C−OTf/OFs, and C−Cl bonds in poly(pseudo)halogenated arenes, displaying superior activity over previous PdI dimer generations for substrates that bear substituents ortho to C−OTf.
- Subjects
PALLADIUM; ALKENES; STYRENE derivatives; FUNCTIONAL groups; AIR
- Publication
Angewandte Chemie, 2020, Vol 132, Issue 49, p22114
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202009115