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- Title
The effect of isomerization of reactant molecules on the early stage of chemical reaction kinetics.
- Authors
Smirnov, L.; Kulagina, T.; Karnaukh, G.
- Abstract
The article presents a study on isomerism effect of reactant molecules on chemical reaction kinetics in the early stage. Mathematical modeling was performed to examine the relationship among the rate constants for the elementary steps (ki) and the equilibrium constants (Ki) of isomers for three kinetic models of isomerization. Results show that dependence of kinetics on isomerization is substantial, not only for first-order reaction but also for homogeneous reactions.
- Subjects
ISOMERISM; CHEMICAL reactions; CHEMICAL kinetics; PHYSICAL &; theoretical chemistry research; MATHEMATICAL models
- Publication
Doklady Physical Chemistry, 2013, Vol 449, Issue 1, p34
- ISSN
0012-5016
- Publication type
Article
- DOI
10.1134/S0012501613030020