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- Title
Radical polymerization behavior of dimethyl vinylphosphonate: Homopolymerization and copolymerization with trimethoxyvinylsilane.
- Authors
Sato, Tsuneyuki; Hasegawa, Makoto; Seno, Makiko; Hirano, Tomohiro
- Abstract
This article discusses a study on the polymerization of dialkyl vinylphosphonates such as di-methyl vinylphosphonate (DMVP) and diethyl vinylphosphonate with dicumyl peroxide (DCPO). The study used Fourier transform near-infrared spectroscopy (FTNIR) and electron spin resonance (ESR) spectroscopy to examine the polymerization. It estimated the overall activation energy of the polymerization and determined the involvement of propagating polymer radicals in the polymerization system.
- Subjects
POLYMER research; POLYMERIZATION research; ELECTRON paramagnetic resonance; DYNAMICS; RESEARCH
- Publication
Journal of Applied Polymer Science, 2008, Vol 109, Issue 6, p3746
- ISSN
0021-8995
- Publication type
Article
- DOI
10.1002/app.28626