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- Title
Microwave-assisted Synthesis, Structure, and Properties of a Heptanuclear Cobalt Cluster with 2-Ethyliminomethyl-6-methoxy-phenol.
- Authors
Huang, Qiu‐Ping; Li, Gui; Zhang, Hai‐Yang; Zhang, Shu‐Hua; Li, He‐Ping
- Abstract
The heptanuclear cobalt cluster [Co7(emmp)6(CH3O)6] ·(ClO4)2 ( 1) (Hemmp = 2-ethyliminomethyl-6-methoxy-phenol) was synthesized by the microwave-assisted reaction of Co(ClO4)2 ·6H2O with 3-ethoxy-2-hydroxy-benzaldehyde (Hehb) and ethylamine in mixed solvent (acetonitrile:methanol = 1:1). Complex 1 was characterized by IR spectroscopy, elemental analysis, and X-ray single-crystal diffraction. The magnetic properties of 1 are discussed. Complex 1 displays dominant ferromagnetic interactions from the nature of the binding modes through μ3-OCH3 and μ2-phenoxo.
- Subjects
COBALT; PHENOLS; BENZALDEHYDE; ETHYLAMINES; INFRARED spectroscopy; X-ray diffraction; MAGNETIC properties
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2014, Vol 640, Issue 7, p1403
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201400009