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- Title
Hydrogen Production from a Methanol-Water Solution Catalyzed by an Anionic Iridium Complex Bearing a Functional Bipyridonate Ligand under Weakly Basic Conditions.
- Authors
Fujita, Ken-ichi; Kawahara, Ryoko; Aikawa, Takuya; Yamaguchi, Ryohei
- Abstract
An efficient catalytic system for the production of hydrogen from a methanol-water solution has been developed using a new anionic iridium complex bearing a functional bipyridonate ligand as a catalyst. This system can be operated under mild conditions [weakly basic solution (0.046 mol L−1 NaOH) below 100 °C] without the use of an additional organic solvent. Long-term continuous hydrogen production from a methanol-water solution catalyzed by the anionic iridium complex was also achieved.
- Subjects
HYDROGEN production; HYDROGEN evolution reactions; METHANOL; WATER conservation; ANIONS
- Publication
Angewandte Chemie International Edition, 2015, Vol 54, Issue 31, p9057
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201502194