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- Title
Palladium/Copper-Catalyzed Oxidative CH Alkenylation/N-Dealkylative Carbonylation of Tertiary Anilines.
- Authors
Shi, Renyi; Lu, Lijun; Zhang, Hua; Chen, Borui; Sha, Yuchen; Liu, Chao; Lei, Aiwen
- Abstract
CH/CN activation: The first palladium/copper‐catalyzed aerobic oxidative CH alkenylation/N‐dealkylative carbonylation of tertiary anilines has been developed. Various functional groups were tolerated and acrylic ester could also be suitable substrates. This transformation provided efficient and straightforward synthesis of biologically active 3‐methyleneindolin‐2‐one derivatives from cheap and simple substrates.
- Subjects
CARBON-hydrogen bonds; CHEMICAL symbiosis; ALKENYLATION; CARBONYLATION; ANILINE; PALLADIUM; COPPER research
- Publication
Angewandte Chemie International Edition, 2013, Vol 52, Issue 40, p10582
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201303911