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- Title
HPCO-A Phosphorus-Containing Analogue of Isocyanic Acid.
- Authors
Hinz, Alexander; Goicoechea, Jose M.; Labbow, René; Schulz, Axel; Rennick, Chris
- Abstract
We describe the isolation and spectroscopic characterization of the heavier phosphorus-containing analogue of isocyanic acid (HPCO), and its isotopologue (DPCO). This fundamental small molecule, which has been postulated to exist in interstellar space, has thus far only been observed at low gas phase concentrations or in inert gas matrices. In this report we describe its synthesis, spectroscopic properties, and reactivity in solution.
- Subjects
ISOCYANIC acid; ISOTOPOLOGUES; MOLECULAR spectroscopy; SMALL molecules; PHOSPHINIDENES; CARBENE analogues
- Publication
Angewandte Chemie International Edition, 2017, Vol 56, Issue 14, p3911
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201700368