We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Aqueous Anion Receptors through Reduction of Subcomponent Self-Assembled Structures.
- Authors
Mosquera, Jesús; Zarra, Salvatore; Nitschke, Jonathan R.
- Abstract
To prepare new functional covalent architectures that are difficult to synthesize using conventional organic methods, we developed a strategy that employs metal-organic assemblies as precursors, which are then reduced and demetalated. The host-guest chemistry of the larger receptor thus prepared was studied using NMR spectroscopy and fluorescence experiments. This host was observed to strongly bind aromatic polyanions in water, including the fluorescent dye molecule pyranine with nanomolar affinity, thus allowing for the design of an indicator-displacement assay.
- Subjects
NUCLEAR magnetic resonance spectroscopy; ANIONS; FLUORESCENT dyes; PYRANINE; SPECTRUM analysis
- Publication
Angewandte Chemie International Edition, 2014, Vol 53, Issue 6, p1556
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201308117