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- Title
Recent Advances in Iodine‐Promoted C−S/N−S Bonds Formation.
- Authors
Zhang, Honghua; Wang, Huihong; Jiang, Yi; Cao, Fei; Gao, Weiwei; Zhu, Longqing; Yang, Yuhang; Wang, Xiaodong; Wang, Yongqiang; Chen, Jinhong; Feng, Yiyue; Deng, Xuemei; Lu, Yingmei; Hu, Xiaoling; Li, Xiangxiang; Zhang, Juan; Shi, Tao; Wang, Zhen
- Abstract
Sulfur‐containing scaffold, as a ubiquitous structural motif, has been frequently used in natural products, bioactive chemicals and pharmaceuticals, particularly C−S/N−S bonds are indispensable in many biological important compounds and pharmaceuticals. Development of mild and general methods for C−S/N−S bonds formation has great significance in modern research. Iodine and its derivatives have been recognized as inexpensive, environmentally benign and easy‐handled catalysts or reagents to promote the construction of C−S/N−S bonds under mild reaction conditions, with good regioselectivities and broad substrate scope. Especially based on this, several new strategies, such as oxidation relay strategy, have been greatly developed and accelerated the advancement of this field. This review focuses on recent advances in iodine and its derivatives promoted hybridized C−S/N−S bonds formation. The features and mechanisms of corresponding reactions are summarized and the results of some cases are compared with those of previous reports. In addition, the future of this domain is discussed.
- Subjects
IODINE; NATURAL products; HYPERVALENCE (Theoretical chemistry)
- Publication
Chemistry - A European Journal, 2020, Vol 26, Issue 72, p17289
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202001414