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- Title
A Systematic Survey of the Reactivity of Chlorinated N<sub>2</sub>P<sub>2</sub>, NP<sub>3</sub> and P<sub>4</sub> Ring Systems.
- Authors
Bresien, Jonas; Eickhoff, Liesa; Schulz, Axel; Suhrbier, Tim; Villinger, Alexander
- Abstract
The reactivity of the four‐membered NP3 ring system [RN(μ‐PCl)2PR] (R=Mes*=2,4,6‐tri‐tert‐butylphenyl) towards Lewis acids, Lewis bases, and reducing agents was investigated. Comparisons with the literature‐known, analogous cyclic compounds [ClP(μ‐NR)]2 (R=Ter=2,6‐dimesitylphenyl) and [ClP(μ‐PR)]2 (R=Mes*) are drawn, to obtain a better systematic understanding of the reactivity of cyclic NP species. Apart from experimental results, DFT computations are discussed to further the insight into bonding and electronic structure of these compounds.
- Subjects
LEWIS bases; LEWIS acids; ELECTRONIC structure; CYCLIC compounds; REDUCING agents; CHLORINE
- Publication
Chemistry - A European Journal, 2019, Vol 25, Issue 71, p16311
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201903410